Preparation of Cationic Polyacrylamide Suspension and Its Application in Oilfield Wastewater Treatment.

Abstract

Cationic polyacrylamide (CPAM) solid particle is one of the most commonly used organic polymer flocculants in oilfield wastewater treatment, but it poses some problems, such as a slow dissolution rate and an easy formation into a "fish-eye" in the process of diluting into aqueous solution. However, the current liquid CPAM products also have some problems, such as low effective content, poor storage stability, degradation in a short time, and high preparation costs. In this paper, a CPAM suspension was successfully prepared with 50.00% CPAM fine powder, 46.87% oil phase solvent, 0.63% separating agent, 1.56% emulsifying and dispersing agent, and 0.94% rheology modifier. This suspension has an effective content of 50.00%. It also showed no separation in 7 days of storage at room temperature, no separation in 30 min of centrifugation at a speed of 2000 rpm, and diluted to a 0.40% solution in just 16.00 min. For 1000 NTU of diatomite-simulated wastewater, the optimal turbidity removal rate of the suspension was 99.50%, which was higher than the optimal turbidity removal rate of 98.40% for the inorganic flocculant polymeric aluminum chloride (PAC). For oilfield wastewater, the optimal turbidity removal rate of the CPAM suspension was 35.60%, which was higher than the optimal turbidity removal rate of 28.40% for solid particle CPAM. In a scale-up test, the CPAM suspension achieved a good application effect.