Evaluation of new hydrophobic association inorganic composite material as coagulant for oilfield wastewater treatment

Abstract

• The hydrophobic association PASS was prepared by a base titration method. • PASS with a small amount of lipophilic group could be improving charge neutralization ability. • The crude water containing polymer was effectively treated. • Floc properties were comparatively investigated. The use of oil recovery technologies has resulted in the weakening of interfacial tension between oil and water in oilfield wastewater due to a large amount of polymer present. This leads to the formation of stable emulsified colloidal systems and increases the difficulty of oilfield wastewater treatment. This study investigated hydrophobically-modified polyaluminium silicate sulphate (PASS-C) as a coagulant for oilfield wastewater treatment. PASS-C was prepared by the condensation polymerisation of Al 2 (SO 4 ) 3 ·18H 2 O with dialysed and hydrolysed KH570 [3-(trimethoxysilyl)propyl methacrylate] under titration with NaAlO 2 and water glass at low temperature. The zeta potential of PASS-C showed that the introduction of hydrophobic groups increased its charge neutralisation ability. Additionally, compared with conventional PASS, PASS-C showed a satisfactory oil removal rate from simulated polymer flooding oily wastewater. When the hydrophobic group content was 1% and the dosage of PASS-C was 140 mg·L –1 , the optimal oil removal rate and turbidity removal rate was 95% and 98%, respectively. The particle size and morphology of the coagulated flocs were characterised by laser particle size analysis and SEM. Compared with PASS, PASS-C formed a larger and more compact floc. These findings indicated that the good flocculability of PASS-C for crude oil wastewater was attributable to the synergistic effects of charge neutralisation, hydrophobic associations and adsorption bridging.