Preparation and characterization of thiocyanate-selective electrodes based on new complexes of copper(II) as neutral carriers

Abstract

Abstract The complexes of hydroxycitronellal ( o -aminobenzoic acid) copper(II) (Cu(II)-HXAB) and salicylaldehyde ( o -aminobenzoic acid) copper(II) (Cu(II)-SHAB) were used as neutral carriers in PVC-based membrane ion-selective electrodes. The electrode based on Cu(II)-HXAB exhibited near-Nernstian potential response to thiocyanate (SCN − ) in a linear range of 1.0 × 10 − 6 to 1.0 × 10 − 1 M with a detection limit of 8.5 × 10 − 7 M and a slope of − 57.3 mV/decade in 0.01 M phosphate buffer solution (pH 5.0). The electrode exhibited high selectivity to SCN − over other tested anions with an anti-Hofmeister selectivity sequence. The selectivity behavior might be discussed in terms of UV–Vis spectrum and infrared spectrum. The transfer process of thiocyanate across the membrane interface was investigated by making use of the AC impedance technique. The electrode containing Cu(II)-HXAB could be applied to thiocyanate analysis in waste water with satisfactory results.