Abstract
The relationship between experimental and theoretical results on the polimerizability of phenylacetylene and its derivatives has been found, and the order of decreasing reactivity of phenylacetylene monomers established. The effect of the position of the substituent on the reactivity of the monomer has been calculated. The absorption bands in the ultraviolet spectra of the monomers have been identified by calculation by Hückel's MO-LCAO method. The most probable sequence of the structural units in phenylacetylene polymers has been established. The factors preventing the production of phenylacetylene polymers of high molecular weight are outlined.
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