Polyethyleneimine-cured epoxy-based solvent tolerant nanofiltration membranes

Abstract

Epoxy-based nanofiltration (NF) membranes have great potential to allow untapped applications such as the treatment of water/solvent mixtures. However, achieving reproducible membrane performance with concurrent high permeances for water/solvent mixtures and high solute rejections remains challenging. Herein, such a solvent-tolerant NF (STNF) membrane with superior performance characteristics is synthesized through optimizing the non-solvent induced phase separation (NIPS) method by simultaneously curing 2 epoxide building blocks (EPON 1009F (20 wt%) and EPON SU-8 (10 wt%)) with hyperbranched polyethylene imine (PEI) in dimethyl sulfoxide (DMSO). As a multifunctional crosslinker, the hyperbranched PEI, compared to the difunctional linear hexane diamine (HDA), increases the synthesis reproducibility, the membrane flexibility and permeability, offering a remarkable water/DMF (80/20) permeance of 5.7 L m-1 h-1 bar-1 and a rejection of rose bengal (1018 g mol−1) of 93.3%. A decreased permeance and rejection was observed when increasing the solvent content in the water/DMF or water/ethanol feed from 0 to 30 wt%, while a change in water permeance occurred before and after water/solvent filtrations. The epoxy-based membrane is also intrinsically stable in many solvents, and is easy to tune and produce, making it an ideal candidate for the purification of solvent-containing wastewaters from e.g., the pharmaceutical and chemical industries.