Poly[dichloridobis(μ2-di-4-pyridyl sulfide-κ2N,N′)cobalt(II)

Jian-Ge Wang,Gui-Ying Zhang,Jian-Hua Qin

doi:10.1107/s1600536809001676

Jian-Ge Wang, Gui-Ying Zhang + Show 1 more

Open Access

https://doi.org/10.1107/s1600536809001676

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Abstract

In the title compound, [CoCl2(C10H8N2S)2]n, the CoII atom is located on an inversion centre and is six-coordinated by four N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octahedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the CoII centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intramolecular C—H⋯N and C—H⋯Cl hydrogen bonds.

Highlights

In the title compound, [CoCl2(C10H8N2S)2]n, the CoII atom is located on an inversion centre and is six-coordinated by four
The bridging bidentate di-4-pyridyl sulfide ligands link the CoII centres into a three-dimensional network
Symmetry codes: (ii) x−1, −y+3/2, z−1/2; (iv) −x+1, y+1/2, −z+3/2; (v) x+1, −y+3/2, z+1/2

Summary

Structure Reports

College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, People’s Republic of China. R factor = 0.027; wR factor = 0.070; data-to-parameter ratio = 14.8. In the title compound, [CoCl2(C10H8N2S)2]n, the CoII atom is located on an inversion centre and is six-coordinated by four. N atoms of four symmetry-related di-4-pyridyl sulfide ligands, and two Cl atoms in trans positions, in a distorted octahedral geometry. The bridging bidentate di-4-pyridyl sulfide ligands link the CoII centres into a three-dimensional network. The four coordinating pyridine groups are donors and acceptors (N atoms) for intramolecular C—H N and C—H Cl hydrogen bonds

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