Abstract

In the title compound, [ZrCl(2)(C(14)H(12)N)(2)(C(4)H(8)O)(2)].1.5C(6)H(6), the Zr atom is pseudo-octahedral, with two Cl atoms in trans positions and two tetrahydrofuran molecules in cis positions. The two 3,6-dimethylcarbazolyl ligands are in cis positions and are canted with respect to one another. The two Zr-N distances are 2.1148 (18) and 2.1236 (18) A, and the N-Zr-N angle is 95.08 (7)degrees. The title compound crystallizes as the benzene solvate, with one of the benzene molecules positioned on an inversion center.

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