Abstract
The crystal structure of the title salt, (C25H22P)[Sn(C6H5)3Cl2] or (PhCH2PPh3)[SnPh3Cl2], consists of [PhCH2PPh3]+ cations and [SnPh3Cl2]− anions in which the SnIV atom is linked to two Cl atoms and three phenyl groups in a trigonal–bipyramidal geometry, with the Cl atoms in trans positions. The cation adopts a tetrahedral geometry. In the crystal, the cations and the anions are connected by C—H⋯Cl hydrogen bonds, leading to an infinite chain propagating along the c direction.
Highlights
Cl atoms and three phenyl groups in a trigonal–bipyramidal geometry, with the Cl atoms in trans positions
The cations and the anions are connected by C—H Cl hydrogen bonds, leading to an infinite chain propagating along the c direction
R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger
Summary
Refinement a Departement de Chimie, Faculté des Sciences et Techniques, Université Cheikh, Anta Diop, Dakar, Senegal, and bCNRS, Université de Bordeaux, ICMCB, UPR 9048, 87 avenue du Dr A. R factor = 0.039; wR factor = 0.102; data-to-parameter ratio = 22.0. (PhCH2PPh3)[SnPh3Cl2], consists of [PhCH2PPh3]+ cations and [SnPh3Cl2] anions in which the SnIV atom is linked to two. Cl atoms and three phenyl groups in a trigonal–bipyramidal geometry, with the Cl atoms in trans positions. The cations and the anions are connected by C—H Cl hydrogen bonds, leading to an infinite chain propagating along the c direction
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
