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Cite Journal: Chinese Journal of Organic Chemistry |  Publication Date: Jan 1, 2012 |
 Citations: 2 |
合成了两种新的分子内给受电子体系N-[2-（2-三丁基锡甲硫基）乙基KB苯二甲酰亚胺（1a）和N-（3-三丁基锡丙基）马来酰亚胺（1b），并在甲醇、乙腈-30％水、乙腈中进行了光诱导单电子转移反应．化合物1a在光诱导下发生分子内单电子转移反应，以很高的产率和区域选择性生成环胺醇2．化合物1b在光诱导下发生分子内单电子转移反应生成环胺醇3，同时有[2-1-2]}环加成副反应产物4生成．以上所有新化合物的结构经质谱和核磁共振谱验证．
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