Photoconductivity and transient response of Al:ZnO:Al planar structures fabricated via a thermal oxidation process

Abstract

We have investigated the photoconductivity and transient response of polycrystalline ZnO films grown using a thermal oxidation technique. Zinc-metal films were grown on c-plane sapphire substrates via non-reactive dc sputter deposition at room temperature with subsequent thermal annealing at 300°C, 600°C, 900°C, and 1200°C. Metal–semiconductor–metal Al:ZnO:Al planar ultraviolet (UV) photodetectors were fabricated via sputter deposition of aluminum contacts. Decreasing photoconductivity is seen for increasing annealing temperature, which is consistent with photoluminescence studies showing a similar decrease in the green-to-UV emission ratio. As-grown photodetectors annealed at low temperature (300°C) over 9h demonstrated a responsivity of ~100mA/W. We also present a phenomenological model of photoconductivity transients in which transient recoveries are fitted with a linear combination of two exponential decays. Although annealing temperature did have a significant effect on photocurrent saturation, there was no such relationship for post-illumination recovery time constants.