Photochromic ceramics for multimode detection of UV-VIS radiation dose

Abstract

Electromagnetic radiation in the ultraviolet-to-visible (UV-VIS) band is closely related to human life, and therefore, accurate measurement of UV-VIS radiation dose is essential. However, there are disadvantages to existing radiation dose equipment: it is cumbersome to operate, takes time to analyze, and lacks multimodal measurements. In this study, a photochromic ceramic with rare earth ions Ho3+ and Yb3+ co-doped Ca2SnO4 host was developed. It produces rapid color switching between light yellow and black under UV and VIS radiation. The XPS and EPR results indicate that oxygen vacancies are important in coloring. Based on the photochromic effect, the intensity of down and up-conversion luminescence can be regulated. The maximum regulation rate is 95 %, higher than most photochromic materials of the same type. A multimode UV-VIS radiation detection method is proposed based on photochromism, down-conversion, and up-conversion luminescence light intensity modulation. The results show that the ceramics respond to a wide spectral range of electromagnetic radiation from UV-VIS with varying degrees, and the best response is to UVB (Ultraviolet Radiation B). A convenient scheme for on-site radiation dosimetry by colorimetry and changes in luminescence intensity was designed to verify the method's reliability. Stability tests have shown that these ceramics have good cyclic stability, making them an ideal detection material for accurate UV-VIS radiation dose detection.