Persistence time bound for subdiffusion based on multidimensional thermodynamic uncertainty relation: Application to an analytically solvable model.

Abstract

The thermodynamic uncertainty relation (TUR) is an inequality showing the tradeoff relationship between the relative fluctuation of current observables and thermodynamic costs. It is one of the most important results of stochastic thermodynamics. There are various applications for TUR, one of which is the recent finding of thermodynamic constraints on the time window in which anomalous diffusion of Brownian particles can occur, including subdiffusion and superdiffusion, which are slower and faster than normal diffusion, respectively. These constraints are quite nontrivial because they are not generally derived from the asymptotic normal-diffusive behavior of the anomalous diffusion itself. In this study, we applied multidimensional TUR to the subdiffusion of Brownian particles obeying multivariate Langevin dynamics with a translationally invariant Hamiltonian in equilibrium. Multidimensional TUR is an improved TUR that includes information on another observable in addition to the one currently being considered. The use of an additional observable yields tighter bounds on the current fluctuation than those obtained using TUR. As an example, we demonstrated our theory using the one-dimensional Rouse model, which is known as a simple and analytically tractable model of polymer chains. We demonstrated that we improved the bounds for the persistence time of subdiffusion of the Rouse model, which became tighter as a more correlated observable with the current was used.