Abstract
A water-soluble binuclear CuII complex, synthesized using a polypyridine-polyamide ligand, was able to catalyze oxygen reduction to water from neutral aqueous solutions. Electrocatalytic results suggested that one CuII center was first reduced by one electron to form a CuIICuI species, which reacted with O2 to give a superoxide radical intermediate.
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Schedule a callMore From: Journal of the Chemical Society Chemical Communications
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