Organophosphate esters in seawater and sediments from the low-latitude tropical sea

Abstract

Little is known about the distribution, transport and fate of organophosphate esters (OPEs) in the low-latitude tropic sea. Fourteen OPEs were measured in seawater and sediments from the Pearl River Estuary (PRE) and South China Sea (SCS). The concentrations of OPEs in seawater and sediments ranged from 7.65–270 ng/L and 9.02–44.9 ng/g dw, respectively. The concentrations of OPEs in surface seawater from the PRE (93.4 ± 16.5 ng/L) were significantly higher than those in SCS (23.6 ± 2.17 ng/L, p < 0.001). OPEs in water from the PRE showed a decreasing trend from upstream to downstream. The salinity of water was an important factor to determine the concentrations of OPEs in the PRE. The annual input of OPEs from the PRE to the SCS was about 304 tons. The concentrations of OPEs in seawater column from the SCS decreased during 5–800 m and showed an increasing pattern from 800 m to 3400 m, indicating that OPEs can transport into deep seawater. TCPP was the most abundant OPEs in water and sediments from the PRE and TCEP was the predominant OPEs in the SCS. This work highlights long-range transport of OPEs by seawater to the deep sea environment.