Abstract

Abstract Charge separation in the singlet and triplet excited states of donor-spacer-acceptor, DSA, molecules can be studied using the flash-photolysis time-resolved microwave conductivity (TRMC) technique. Highly dipolar, DSA states with microsecond lifetimes can result from Intersystem crossing and through-bond coupling for π-bond conjugated and sigma-bond separated donoracceptor compounds respectively.

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