Optimized scratch adhesion for TiSiN coatings deposited by a combination of DC and RF sputtering

Abstract

This paper outlines an experimental study of the TiSiN coatings deposited using a combination of direct current (DC) and radio frequency (RF) PVD magnetron sputtering (DR-PVD) on high speed steel (HSS) substrates. An L9 Taguchi orthogonal array was used to conduct the experiments for finding the optimum process parameters. Four process parameters, (1) RF power, (2) DC power, (3) nitrogen to argon (N2/Ar) gas ratio and (4) deposition time were considered. The surface structure and composition of selected coating samples were studied by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The critical load in the micro-scratch test was used as a measure of scratch adhesion. Investigations of the scratch tracks were viewed by an optical microscope. The results showed that higher scratch adhesion strength was achieved using RF power of 100W, DC power of 500W, N2/Ar ratio of 1:2.5 and a deposition time of 6h. Optimization resulted in an increase of the critical load value from 827mN to 1371mN, signifying an improvement of over 65%.