Abstract
The limitations of expanding the pressure of a binary mixture of hard spheres as a power series in the diameters of the spheres is investigated. It is shown that such an expansion cannot give the correct monodisperse virial coefficients, while fulfilling certain exact conditions for diameter ratios of zero and one. Imposing the correct virial coefficients is shown to be difficult, without making substantial changes in the functional form of the pressure equation, for a reasonable choice of high virial coefficients.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
