Abstract

Abstract The full spectrum of occupied and unoccupied σ and π orbitals is presented for solid C60, C70, and graphite, using Cls emission and absorption spectroscopy. There are significant diffcrences between C60 and C70, and even larger changes relative to their infinite analog graphite (C∝). A comparison is made with photocmission and inverse photoemission results, along with first principles quasiparticle calculations.

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