Abstract
The differences in the acid–base properties and nucleophilic reactivity within a series of 1-methyl-3-alkyl-2-(oximinomethyl)imidazolium halides in the dissociation of 4-nitrophenyl diethyl phosphate were analyzed. The positive deviation of points for comicellar systems derived from compounds of this series from the Bronsted plot was shown to be related to a decrease in the values of p $$ K_{\text{a}}^{\text{app}} $$ of the oximate fragment of the functional surfactants due to the action of the added cationic codetergent (CTAB).
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