Abstract
An anomalously large increase was found in the rate of cleavage of 4-nitrophenyl 4-toluenesulfonate (∼13000 times) and diethylphosphate (∼550 times) by the zwitterionic micelles of 1-cetyl-3-(2-hydroxyiminopropyl)imidazolium chloride and bromide. Detailed kinetic and thermodynamic analysis of these processes made it possible to establish that the main factor responsible for the high rates of reaction in the micellar phase is the concentration of the reagents.
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