Abstract
Nitrogen and proton coupling constants for a series of 1- and 2-naphthyl t-butyl nitroxides have been evaluated using both n.m.r. and e.s.r. techniques. McLachlan MO calculations on 2-naphthyl t-butyl nitroxide give values for the free spin densities on the ring positions which are in reasonably good agreement with those determined experimentally. Similar agreement for 1-naphthyl t-butyl nitroxide was not obtained.
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More From: Journal of the Chemical Society, Perkin Transactions 2
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