Abstract

Near-infrared (NIR) spectroscopy has gained increased attention for the qualitative and quantitative evaluation of textile and polymer products. Many NIR instruments have been commercialized to identify the natural and synthetic fibers; however, there is a strong need to have NIR database of these high-performance fibers to detect contraband textile materials rapidly and quantitatively. In this study, NIR spectra of PLA, Kevlar, Spandex and Sorona woven fabrics were collected and studied by several calibration models to identify the fibers. The results indicated that these four innovative fibers had been successfully distinguished by their NIR spectra in combination with preprocessing of 1/X transformation, SNV, and 2nd Savitzky-Golay derivative as well as principal-component-analysis (PCA-) based chemometric methods. Our promising results suggest that NIR spectroscopy is an effective technique to anticounterfeit innovative fibers.

Highlights

  • Near-infrared (NIR) spectroscopy has gained increased attention for the qualitative and quantitative evaluation of textile and polymer products

  • The combination of a serial of preprocessing methods has been determined in order to produce a principal component analysis (PCA) model separating these fibers

  • The spectral regions between 7100 and 9100 cm−1 were selected for multivariate analysis based on Principal component analysis (PCA) model

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Summary

Introduction

Near-infrared (NIR) spectroscopy has gained increased attention for the qualitative and quantitative evaluation of textile and polymer products. The NIR spectroscopy region extends from approximately 800 nm to 2500 nm in the electromagnetic spectrum. Different materials absorb NIR energy at different wavelengths. NIR spectroscopy measures overtones and combinations of the fundamental molecular vibrational transitions that occur in the mid-infrared region. These absorbance wavelengths (and the corresponding frequencies) form a unique NIR signature depending on the chemical and physical properties of the materials. This method is nondestructive and environmentally friendly. NIR spectroscopy has become a widely used analytical technique for process control, for quality assessment, and for determining the unknowns of complex mixture [1]

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