Abstract
Landau-de Gennes mean-field model predicts the discontinuous transition for the isotropic – nematic (I-N) transition, associated with uniaxial ordering and a quadrupolar order parameter in three dimensions. This report shows pressure-related dielectric studies for rod-like nematogenic pentylcyanobiphenyl (5CB) and its nanocolloids with BaTiO3 nanoparticles. The scan of the dielectric constant revealed the near-continuous I-N phase transition in the compressed nanocolloid with a tiny amount of nanoparticles (x = 0.1%).For the nematic phase in 5CB and its x = 1% nanocolloid the enormous values of the dielectric constant and the bending–type, long-range pretransitional behavior were detected. The impact of prenematic fluctuations was also noted for the ionic-related contribution to dielectric permittivity in the isotropic liquid phase. For the high-frequency relaxation domain, this impact was tested for the primary relaxation time pressure evolution and the translational–orientational decoupling.
Published Version
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