Abstract
Mean hyperfine field H and isomer shifts I S obtained from Mössbauer measurements for rf sputtered (SP) and liquid quenched (LQ) Fe 1 − x B x (0.12 ⩽ x ⩽ 0.60 for SP and 0.13 ⩽ x ⩽ 0.24 for LQ) samples are compared with values for crystalline α-Fe, Fe 3B, Fe 2B and FeB. H and IS for both kinds of samples are in good agreement with those for the crystalline phases up to x ∼ 0.35. For SP films we observe a deviation from this tendency above x > 0.35. It seems that this effect is caused by chemical inhomogeneities in our films.
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