Abstract

The mononuclear hydrolysis constants of titanium (IV) have been calculated by means of partition data for titanium (IV) between aqueous solutions 0·1 M in perchlorate and organic solvents containing 8-hydroxyquinoline in chloroform and TTA in benzene. The experimental data can be explained in terms of the following equilibria: ▪ ▪ ▪ Since the existence of Ti 4+ is ruled out in the pH range 0·5-3, the solubility product of titanium (IV) hydroxide [TiOH] 3+[OH −] 3 has been determined. The formation constants of the complexes titanium −TTA and titanium-oxine in water solutions have been calculated by taking into account hydrolytic equilibria.

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