Abstract

The asymmetric unit of the title compound, [Sn3(CH3)6S3], contains two molecules with twist-boat conformations. There are intermolecular S⋯H (2.929 Å), S⋯S (3.433 Å), S⋯C (3.465 Å) and C⋯H (2.898 Å) inter­actions in addition to prominent intermolecular Sn⋯S inter­actions of 3.692 and 3.769 Å.

Highlights

  • The asymmetric unit of the title compound, [Sn3(CH3)6S3], contains two molecules with twist-boat conformations

  • Authors are grateful to the CSIR, New Delhi, for financial assistance in the form of a JRF (AK) and a CSIR Project (NS)

  • The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry

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Summary

Crystal data

G. Kociok-Köhnb a Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi 221005, India, and bSchool of Chemistry, University of Bath, Bath BA2 7AY, England R factor = 0.030; wR factor = 0.067; data-to-parameter ratio = 40.7. The asymmetric unit of the title compound, [Sn3(CH3)6S3], contains two molecules with twist-boat conformations. There are intermolecular S H (2.929 Å), S S (3.433 Å), S C (3.465 Å) and C H (2.898 Å) interactions in addition to prominent intermolecular Sn S interactions of 3.692 and 3.769 Å.

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