Abstract

NMR was used to study the behaviour of several aromatic polyamides and polyimides over the temperature range of 77–700°K and low molecular weight compounds which simulate polymer chain fragments. Assuming that torsional vibrations of planar groups and units are the main type of molecular motion in these systems, a study was made of actual features of this type of motion and their effect on thermal and physical properties of polymers was investigated. Effects of restricting the intensity of molecular motion as a result of molecular interaction in layers of plane parallel groups are important.

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