Abstract
Abstract In this work, the equilibrium CO2 solubilities of the aqueous N-(2-hydroxyethyl) pyrrolidine (N-(2-HE) PRLD) at different concentrations (1.0 mol/L–5.0 mol/L) were measured at different temperatures (298 K–333 K) and pressures (8 kPa–101 kPa), using a vapor–liquid equilibrium apparatus. Four semi-empirical thermodynamic models (Cf model, Kent–Eisenberg model, Hu–Chakma model and Li–Shen model) were used to correlate and predict the CO2 solubility data of the N-(2-HE) PRLD-CO2–H2O system. The results showed that the Hu–Chakma model, which is one of the models that incorporates the effect of amine concentration and CO2 loading, and accounted for nonideality caused by higher temperature, species concentrations and CO2 loadings, was best able to predict results that are in agreement with the experimental vapor–liquid equilibrium measurements in this work.
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More From: Journal of the Taiwan Institute of Chemical Engineers
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