Mixed reaction gold as versatile plating solution for ENIG, ENEPIG and EPAG plating

Abstract

The surface finish on a printed circuit board (PCB) or substrate serves as surface protection and at the same time enables a variety of assembly techniques. Depending on which final finish is selected it allows for e.g. soldering connections or wire bonding by Al, Au or even Cu-wires. Surface finishes are typically characterized by different metal layers, including tin, nickel, palladium or gold. In this context the electroless or immersion plating of gold has a long history in the electronics industry. The gold plating represents a key step in different finish systems such as electroless nickel/immersion gold (ENIG), electroless nickel/electroless palladium/immersion gold (ENEPIG) and electroless palladium/autocatalytic gold (EPAG). ENIG, ENEPIG and EPAG finishes are characterized by their capabilities to be used as solderable and wire-bondable finish with specific benefits for ENEPIG and EPAG such as enhanced solder joint reliability and gold-wire bondability. In this paper an overview is given on the different types of electroless gold plating electrolytes from fully immersion type and autocatalytic type to mixed reaction type gold electrolytes. The details of the various plating mechanisms are presented, and the different properties and capabilities of these electrolytes are compared and explained based on the respective mechanisms. The presented study investigates the performance of a gold electrolyte of a mixed reaction type looking into the layer properties as well as the soldering and bonding capabilities. The results show that a mixed reaction gold electrolyte can be capable for versatile application- ENIG, ENEPIG and EPAG. The capability of the process was tested with respect to the solder wetting performance, solder joint reliability, wire bonding performance, corrosive attack to the nickel and thickness distribution. It can be shown that this gold process passes or exceeds all related industry standards and target requirements for ENIG, ENEPIG and EPAG final finishes.