Abstract

A screening method to evaluate Suzuki–Miyaura and Buchwald–Hartwig coupling reactions under aqueous surfactant conditions has been established, leading to high yielding and highly selective Suzuki–Miyaura and Buchwald–Hartwig reactions under mild reaction temperatures and ecologically improved conditions. The screening method highlighted the utility of Buchwald–Hartwig third generation precatalysts for unprecedented high conversion Buchwald–Hartwig C–N coupling reactions in water.

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