Abstract
Herein we report the preparation, characterization and the catalytic ability of novel Pd(II)-β-cyclodextrin complex as an efficient nanocatalytic system for the Suzuki–Miyaura carbon-carbon (CC) coupling reaction in water. The presented novel Pd(II)-β-cyclodextrin complex catalyst was characterized by TGA, FT-IR, XRD, NMR and atomic absorption analysis. Also, by using the Pd(II)-β-CD complex as a homogeneous catalyst, we have developed an efficient protocol for suzuki-Miyaura coupling reaction of aryl boronic acids with aryl halides in neat water with high turnover frequencies (TOFs) for the synthesis of unsymmetrical biaryls. The catalyst can be recycled and reused multiple times to catalyze the coupling reaction.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
