Abstract

(1−x)SrTiO3–xCa0.61Nd0.26TiO3 (0.6 ≤ x ≤ 0.9) ceramics are prepared through the conventional solid-state route. The XRD results suggest that a single CaTiO3-like perovskite structure is formed in the range of 0.6 ≤ x ≤ 0.9. Microscopic surface textures and microwave dielectric properties have been investigated by scanning electron microscopy, thermal dilatometry and microwave resonant measurement at the frequency 2–4.2 GHz, respectively. As the x value increases from 0.6 to 0.9, the dielectric constant (e r ) decreases due to the smaller ionic polarizability of Ca0.61Nd0.26TiO3 than that of SrTiO3. The (1−x)SrTiO3–xCa0.61Nd0.26TiO3 (0.6 ≤ x ≤ 0.9) ceramics sintered at temperatures 1,350–1450 °C for 4 h are accompanied by a decrease in e r from 166.8 to 115.7 and a decrease in the temperature coefficient of resonant frequency from +499.6 to +276.8 ppm/ °C, while a increase in the product of dielectric Q value and resonant frequency (Q × f) from 4,945 GHz (at 2.44 GHz) to 11,850 GHz (at 2.87 GHz). The resultant dielectric properties have made (1−x)SrTiO3–xCa0.61Nd0.26TiO3 ceramics as very interesting materials for microwave communication and passive component applications.

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