Microstructure refinement and strengthening mechanisms of bimodal-sized and dual-phased (TiCn-Al3Tim)/Al hybrid composites assisted ultrasonic vibration

Abstract

Relatively high strength and good ductility are rarely obtained simultaneously in aluminum matrix composites. In the present work, dual-phased TiCn-Al3Tim (n: nanosized TiC particles and m: micron-sized Al3Ti particles) particles were in situ synthesized in an Al-Ti-C system via the combustion synthesis method. Subsequently, (TiCn-Al3Tim)/Al hybrid composites were readily fabricated at high addition levels (0, 1, 3, 5 and 7 vol%) via the re-melting and diluting method assisted ultrasonic vibration. Then, the isolated influences of the dual-phased TiCn-Al3Tim particles on the solidification behaviors, microstructure evolution and mechanical properties, at both ambient- and elevated-temperatures, of aluminum alloys were systematically investigated. The experimental results revealed that the α-Al dendrites were substantially refined with a reduction of up to 4 times when compared with that of the unreinforced base alloy. Furthermore, at ambient temperature, 5 vol% (TiCn-Al3Tim)/Al exhibited the optimum comprehensive mechanical properties, and the yield and ultimate tensile strength were 124.3% and 165.2% higher than those of the unreinforced base alloy, whilst the fracture strain was not sacrificed. Theoretical calculations suggest that thermal-mismatch and Orowan strengthening effects contributed most to the yield strength increment, whereas the favourable fracture strain was achieved mainly due to grain refinement. Moreover, at elevated temperature (453 K), the yield strength and ultimate tensile strength were improved by 327.8% and 236.1%, respectively, whilst the fracture strain was still at a relatively high level of 29.2%. The improved thermal resistance primarily resulted from the pinning effects of the TiCn-Al3Tim particles on the grain boundaries and dislocations.