Abstract
Electrostatic spray deposition (ESD) was used to deposit La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) cathode films on dense Ce0.9Gd0.1O2−δ (CGO) electrolytes. LSCF films with different morphologies were obtained by varying the substrate temperature (250 to 450 °C), nozzle-to-substrate distance (15–45 mm) and precursor solution flow rate (0.34 to 1.5 mL h–1). A detailed study on the influence of the microstructure of LSCF cathode films on electrochemical behavior is reported. Resulting films can be classified according to their morphology as dense, cracked and coral microstructures. Detailed microstructural characterization was made by SEM and completed with 3D focused ion beam–scanning electron beam (FIB-SEM) tomography of representative samples. Surface areas of the cathode/pore interfaces, normalized by the cross-sectional area of the support, were found to be 2.0, 24.7, and 28.2 for dense, cracked and coral microstructures, respectively. Electrical measurements were performed at intermediate temperatures (400–600 ...
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call