Abstract
A microscopic approach based on the first-principles effective Hamiltonian is developed to study the polarization response in temperature-graded ferroelectrics. This approach has been applied to the case of (Ba(0.75)Sr(0.25))TiO₃ alloy. A comparison of the computational results with available experimental data attests to the remarkable accuracy of the present approach. Our computations reveal a strong anisotropy in the response of polarization to the temperature gradient (TG). In particular, the polarization offset along the direction of TG is an order of magnitude lower than in the perpendicular direction. The large as well as the small TGs are considered and found to yield qualitatively different polarization field responses. Among other striking findings are (i) the coexistence of different phases in chemically homogeneous regions, (ii) formation of low-symmetry phases, and (iii) thermally controlled polarization rotation.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
