Metamorphism, geochemistry, and carbon source on sedimentary‐metamorphic graphite deposits in eastern Shandong, China

Abstract

Eastern Shandong is one of the most economically important regions for ore‐producing sedimentary‐metamorphic graphite deposits in China. The Liugezhuang and Daliangzikou graphite deposits in the Pingdu–Laixi Graphite Belt are typical examples. The ores in the Liugezhuang deposit and Daliangzikou deposit are typically gneiss/granulite type and biotite granulite type, respectively. Graphite occurs as stratabound layers of slender flakes associated with biotite, clinopyroxene, and plagioclase and as slender flakes and disseminated grains associated with biotite and filling tiny fractures in mineral grains. The mineral associations indicate that the ore rocks can be classified into four metamorphic facies: (a) amphibolite granulite facies, Cpx (Hy) + Opx (Di) + Pl ± Hbl ± Qz; (b) amphibolite facies, Hbl + Pl + Cpx (Opm) + Ep + Bt + Ms + Qz ± Chl ± Mic; (c) high‐grade greenshist facies, Hbl + Pl + Ep + Bt + Chl + Qz ± Cpx; and (d) low‐grade greenshist facies, Ep + Chl + Pl + Bt + Ms + Chl + Qz + Rt. Study of the variation in graphite crystals and fixed carbon with increasing metamorphic grade suggests that more than one metamorphism process (graphitization) occurred during ore formation. Geochemical analysis indicates that the primary condition under which the Liugezhuang and Daliangzikou graphite deposits formed was a marine facies sedimentary environment of which the material source was terrestrial weathering detritus and compounds and also a participation of terrestrial material in the graphite deposits. Trace element data suggest that the sedimentary condition was from a reducing condition in the Liugezhuang graphite deposit to a weaker reducing condition in the Daliangzikou graphite deposit, whereas samples from a Jingshan Group stratum show multiple oxidation–reduction conditions but dominantly oxidation. Carbon isotope analysis indicates that the carbon source of the Liugezhuang graphite deposit was organic, whereas that of the Daliangzikou graphite deposit was mainly organic carbon but with some inorganic participation.