Abstract

This paper demonstrates the benefits of using a metallic foam support within molten carbonate fuel cell (MCFC) cathodes. A state-of-the-art fabrication process based on tape casting has been developed to produce microporous electrodes with a nickel foam scaffold. Surfactant was added to control the depth to which the slurry infiltrated the foam. New cathodes were used as an alternative to the traditional cathode in the single cell assembly and were tested for power density. Mechanical properties were compared with the current state-of-the-art. The results show that the use of metallic foams for high temperature fuel cell electrodes is beneficial from the technological point of view, especially in larger scale production. It was also found that the resultant continuous metallic structure of the microporous electrodes delivered a slight enhancement to fuel cell power density.

Highlights

  • This paper demonstrates the benefits of using a metallic foam support within molten carbonate fuel cell (MCFC) cathodes

  • The electrodes within a single cell are characterized by open porous microstructures designed to facilitate phenomena such as gas diffusion, surface reactions, capillary action and ion transport

  • According to the generally accepted theory, electrochemical reactions in an MCFC occur at the triple phase boundary (TPB) between the catalyst surface, electrolyte and pore space

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Summary

Metallic foam supported electrodes for molten carbonate fuel cells

T. Wejrzanowski a,⁎, K. Cwieka a, J. Skibinski a, T. Brynk a, S. Haj Ibrahim a, J. Milewski b, W. Xing c a Warsaw University of Technology, Faculty of Materials Science and Engineering, Woloska 141, 02-507 Warsaw, Poland b Institute of Heat Engineering, Warsaw University of Technology, Nowowiejska 21/25, 00-665 Warsaw, Poland c SINTEF Materials and Chemistry, Sector for Sustainable Energy Technology, Forskningsveien 1, NO-0314 Oslo, Norway article info Article history: Received 2 April 2020 Received in revised form 7 May 2020 Accepted 5 June 2020 Available online 6 June 2020 Keywords: Open-porous materials Molten carbonate fuel cells Foam supported electrodes

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