Marangoni instability in the iodate–arsenous acid reaction front

Abstract

Horizontally propagating chemical fronts leading to the formation of a single stable convection roll are investigated in the iodate-arsenous acid reaction with arsenous acid stoichiometrically limiting, leaving the surface active iodine present in the product mixture. In sufficiently thin solution layers with open upper surface, the contribution of Marangoni instability is significantly enhanced. Acting in the same direction as buoyancy driven instability, it distorts the entire tilted reaction front that becomes 50% more elongated. The corresponding three-dimensional calculations based on the empirical rate-law of the reaction corroborate the experimental findings.