Abstract

By classical statistical perturbation calculus, successive contributions to many-molecular correlation -induced optical anisotropy in simple fluids are calculated taking into account linear dipolar polarizability induced by dipolar and quadrupolar interaction fields, as well as non-linear dipolar polarizabilities due to fluctuating dispersional and octupolar fields. In the approximation of binary correlations (which are sufficient for inducing optical anisotropy) all contributions are positive, whereas three-, and more- molecular correlations can lower or enhance (according to the structure of near order) the anisotropic scattering of light, as confirmed by the latest experiments in liquefied and condensed noble gases.

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