Abstract
AbstractFerrocenylaldimines (Fc‐CH=N‐R) were prepared by condensation of Schiff base of formylferrocene with polyacenylamines RNH2; R = naphthyl, anthracenyl and pyrenyl groups. This step was followed by oxidation with FeCl3 to give [Fc‐CH=NR]‐FeCl3 adducts. The electronic state of iron in these adducts was investigated by means of 57Fe Mössbauer spectra except for [Fc‐CH=N‐Pyr]‐FeCl3 showed that only a doublet was observed at ambient temperature. As the temperature was decreased below 200 K, additional magnetic hyperfine splitting was observed characteristic of ferric oxide.
Full Text
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call