Abstract

AbstractA series of ferrocenylaldimines (Fc‐CH=N‐R) has been prepared by Schiff base condensation of formylferrocene with polyacenylamines RNH2 where R = naphthyl, 5,6,7,8‐tetrahydronaphthyl, anthracenyl, and pyrenyl groups. This step was followed by oxidation with TCNQ to give [Fc‐CH = N‐R][TCNQ]2 salts. The electronic state of iron in these compounds was investigated by means of57Fe Mössbauer spectroscopy.

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