Abstract

Raman study of flexure stressed poly(methyl methacrylate) (PMMA) plates at the frequency range of libration mode (80 cm−1), boson peak (14 cm−1), and quasi-elastic light scattering (QLS) (below 20 cm−1) is presented. The reversible changes in the vicinity of the Rayleigh line were attributed to partial disturbance of the midrange order due to stress-induced redistribution of random fluctuations of orientation. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 1133–1136, 2000

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