Abstract
Amphi‐syn stereoisomers with 62:38 compositional ratio existing in 3‐nitrolawsoneoxime [S.Y. Rane et al., 1990] leads to two configurational forms in its copper (II) complex 1 viz. [Cu(NO2‐LwOx)2] · 3H2O. The D4h:D2h geometries of 1 have been detected in 70:30 ratio from solution EPR spectra. Line width alternation effect with superimposition of metal‐ligand hyperfine splits lead to anisotropic magnetic parameters. Best fitted bonding parameters of 1 are compared with O∧O and N∧O donor complexes.
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