Abstract

ABSTRACT: The objective of this work was to study the influence of adjuvants on leaching and persistence of sulfentrazone in a Red-Yellow Ultisol. The soil was stored in PVC columns of 10 cm diameter and 50 cm length. The treatments were composed of sulfentrazone mixed with six adjuvants (Adesil®, Break-Thru®, Assist®, Hoefix®, Fera® and Nortox® Vegetable Oil), a treatment with sulfentrazone without any adjuvant and a treatment without the herbicide. In the treatments with sulfentrazone, the herbicide was applied at a rate of 1.0 kg ha-1 at the top of the columns, and 12 hours after application, the columns were subjected to simulated rainfall (60 mm). To confirm leaching of sulfentrazone, soil samples were collected every 5 cm up to 50 cm in each column and transferred to 300 cm3 pots to conduct a bioassay using the species Sorghum bicolor. At 21 days after emergence (DAE) of sorghum, visual assessment of intoxication was performed and shoot dry matter percentage was determined. To determine the influence of adjuvants on persistence of sulfentrazone in the soil, new sorghum seeds were planted as soon as the sorghum plants from the first planting were cut; also, phytotoxicity scores were assigned and shoot dry matter was determined at 21 DAE. This procedure was repeated up to 173 days after herbicide application, when the plants showed no more visual symptoms of intoxication. The adjuvant Break-Thru® was effective at reducing leaching of sulfentrazone. The presence of adjuvants applied together with sulfentrazone did not influence the persistence of the herbicide in the study soil. Persistence of sulfentrazone lasted for 143 days.

Highlights

  • One of the pre-emergent herbicides most frequently used in agricultural systems is sulfentrazone N-[2,4-dichloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazole1-yl]phenyl]methanesulfonamide

  • This molecule is recommended for weed control in crops such as soybeans, sugar cane, coffee and eucalyptus (Rodrigues and Almeida, 2011)

  • Based on the values determined in the soil analyses, the following parameters were calculated: effective and potential cationic exchange capacity (CEC) (5.26 cmolc dm-3 and 7.36 cmolc dm-3, respectively), total exchangeable bases (TEB) (5.26 cmolc dm-3), aluminum saturation percentage (m) (0.0%) and base saturation percentage (V) (71.5%)

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Summary

Introduction

One of the pre-emergent herbicides most frequently used in agricultural systems is sulfentrazone N-[2,4-dichloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazole1-yl]phenyl]methanesulfonamide. This molecule is recommended for weed control in crops such as soybeans, sugar cane, coffee and eucalyptus (Rodrigues and Almeida, 2011). Water solubility changes on the basis of pH:110 780 and 1,600 mg L-1 at pH 6.0, 7.0 and 7.5, respectively (Tomlin, 2011) This herbicide may present high persistence and mobility in soil and aquatic systems (EPA, 2015), and possibly cause serious environmental problems, in addition to increasing the risk of intoxication of sensitive succeeding crops (carryover effect)

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