Abstract
By means of collinear laser spectroscopy at ion beams of Ar+, S+ and Cl+ the isotope shifts of a total of twelve lines could be measured. All the lines are of the type 3pn−1 3d→3pn−14p (3p n being the proper ground configuration of the ions). All the measured shifts are unusually large and prevailingly due to a strong specific mass effect or momentum correlation of the 3d electron with the innerp-shells. The measured shifts could be quantitatively reproduced by computation of the inherent Vinti integrals.
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