Abstract
The kinetics of the reactions designated in the title have been studied as a function of amine concentration in acetonitrile, dimethyl sulphoxide, and (for piperidine and n-butylamine only) methanol. In all the solvents studied, the reactions of the secondary amines are base-catalysed : those of the primary amines are not. The results are interpreted in terms of the generally accepted mechanism of nucleophilic aromatic substitution.
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Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
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