Abstract
Chlorination reactions in anhydrous or glacial acetic acid as the solvent occur at room temperature through the combination of the soft acid, C12, with various soft bases: linear pentenes (10); methyl transcinnamate (3); and 4-substituted arenesulfenyl chlorides (5). The kinetics for the normal chlorinations involve a first order dependence upon the halogen and on the soft base, and in each case the proposed mechanisms postulate ionic chlorine-containing species as the intermediate. The overall process can be formalized by equation 1.
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