Isolation of a Cd-Based Coordination Polymer Containing Mixed Ligands: Time- and Temperature-Dependent Synthesis, Sulfonamide Antibiotics Detection, and Schottky Diode Fabrication.

Abstract

In this study, we present a new cadmium(II)-based two-dimensional coordination polymer [Cd (L)(NA)(H2O)] (L = Iminol form of N-nicotinoyl glycinate, NA = nicotinate), 1, containing two linkers generated from N-nicotinoyl glycine. A comprehensive investigation was carried out during the synthesis of the coordination polymers by varying the reaction time interval and temperature, and it revealed the formation of three distinct phases, of which two phases were previously reported and one was a new compound (1). The structure of compound 1 was determined by single-crystal X-ray diffraction, and it shows a corrugated layer structure with hydrogen bond interactions leading to three-dimensional supramolecular arrangements. Compound 1 exhibited strong emission at 420 nm when excited at 260 nm in an aqueous medium. The emission behavior of this compound was used for the detection of various sulfonamide antibiotics, sulfadiazine, sulfamethazine, sulfachloropyridazine, sulfameter, sulfaquinoxaline, and sulfathiazole, in the presence of common water pollutants. The luminescence quenching response of compound 1 to sulfonamide antibiotics was significant, ranging from 81 to 94%, and the detection sensitivity reached parts per billion (ppb) levels (226-726 ppb). Compound 1 also used for the fabrication of Schottky diode devices with a barrier height of 0.86 eV along with an excellent ideality factor of 1.24.