A Zn(II) coordination polymer as a dual sensor for ppb level detection of antibiotics and organo-toxins in a green solvent

Abstract

Herein, we describe the synthesis of a new fluorescent d10 coordination polymer, [Zn2(CFDA)2(BPEP)]n·nDMF (CP-1) under solvothermal reaction condition using zinc metal ion. In CP-1, Zn(II) ion along with CFDA and BPED ligand forms a 2-fold self-interpenetrated 3D coordination polymers. This CP-1 is characterized by the single crystal X-ray diffraction (SCXRD), powder X-ray diffraction (PXRD), infrared spectra, optical microscope image and thermogravimetric analysis and the framework is found to maintain its structural stability in different solvents. The framework (CP-1) detected antibiotics (NFT (nitrofurantoin) and NZF (nitrofurazone)) and organo-toxin trinitrophenol in aqueous dispersed medium. Apart from the fast responsive (10 s), the detection limit for them was found at ppb level. The detection of these organo-aromatics were also comprehended by the colorimetric response through solid, solution and low cost paper strip technique i.e., triple mode recognition capability. The probe is re-usable without changing in its sensing efficiency and in addition, it has been applied for the detection of these analytes in the real field specimens (soil, river water, human urine and commercial tablet). The sensing ability is established by in-depth experimental analysis and the life time measurement where mechanism such as photo induced electron transfer (PET), fluorescence resonance energy transfer (FRET), inner filter effect (IFE) was recognized. The presence of guest interaction sites on the linker backbone in CP-1 induces diverse supramolecular interaction with the targeted analytes results to bring them in proximity for the occurrence of these sensing mechanism. The Stern-Volmer quenching constant values of CP-1 for the targeted analytes are admirable and the low detection limit (LOD) values for NFT, NZF and TNP are found to be 34.54, 67.79 and 43.93 ppb respectively. Further, the DFT theory is carried out in details to justify the sensing mechanism.