Abstract
The rate and products of the reaction between each of a range of deactivated substituted benzenes and the tri-iodine cation, in sulphuric acid solution, have been investigated. The rate constants may be correlated by the electrophilic substituent constants σ+ giving a value for the reaction constant ρ=–6·4. The kinetic isotope effect for the iodination of benzoic acid was found to be kH/kD= 2. Further details of the solvent effect are reported.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
